
ISSN: 3006-2950 (Print)
ISSN: 3006-2969 (Online)
CODEN: ASYMAJ
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I am delighted to see the launch of this Special Issue, “Advances in Asymmetric Catalysis: From Mechanisms to Applications”, edited by Guest Editors Mario Waser and Shengcai Zheng. Having had the opportunity to propose the theme of this Special Issue, I am especially pleased to see it come to fruition. The synthesis of chiral compounds in high optical purity is critically important in medicinal and agrochemical chemistry. K. Barry Sharpless, Ryoji Noyori, and William S. Knowles were awarded the 2001 Nobel Prize in Chemistry for their pioneering contributions to asymmetric oxidation and asymmetric reduction catalysis. These transformations have been primarily achieved using transition-metal catalysts based on elements such as titanium, ruthenium, and rhodium. Subsequently, a wide variety of asymmetric carbon–carbon bond-forming reactions employing chiral Lewis acid and chiral Lewis base catalysts were developed, leading to remarkable advances in asymmetric catalysis.
In a recent review, “Size and/or charge asymmetry effects in coulombic fluids in the presence of external fields: From simple electrolytes to molten salts”, Guerrero-García, Biophysical Chemistry 282, 106747 (2022), one of the present authors analyzed some consequences of breaking the symmetry in the valence and/or ionic size of charged fluids, such as aqueous electrolytes, macroion solutions, or molten salts, when ion correlations and ionic excluded volume effects were taken into account. In this review article, we would like to discuss some additional effects of breaking the symmetry in the valence and/or size of charged particles of coulombic fluids (i) next to a rigid cylindrical charged polymer, and (ii) in the electrostatic properties of an electrical double layer planar supercapacitor. These effects were studied in approaches beyond the classical non-linear Poisson-Boltzmann theory of point ions, by using classical integral equations theory, the Modified Poisson-Boltzmann theory, and Monte Carlo simulations in implicit solvent. As a result, the relevance of the asymmetry in the valence and/or size of charged particles, at microscopic level, is illustrated here either in simple electrolytes or in aqueous colloidal suspensions of macroions, when both are under the influence of an external electric field.
The purpose of this study was to determine whether inside-outside foot asymmetries were observed when running multiple bases in baseball. Fifty-four trained male high school baseball position players performed two linear 54.7-meter sprints and two home-to-second base sprints. Ground contact time (GCT), stride length (SL), and average push-off and impact were quantified using inertial measurement unit foot pod technology. The sprints were divided into four segments (0–13.7 m; 13.7–27.4 m; 27.4–41.1 m; 41.1–54.7 m) for both curvilinear segments (C):C1–C4, and linear segments (L):L1–L4. The primary findings of this study were that for linear sprinting, GCT was not significantly different between feet across all segments, but SL was significantly shorter (L2–L4) in the outside foot (−0.76% to −1.34%; ES = −0.20 to −0.37) and push-off were significantly greater (L1–L4) in the outside foot (2.95% to 4.39%; ES = 0.27 to 0.40), with significantly greater outside-foot impact only in L1 (5.63%; ES = 0.29). In curvilinear sprinting, the inside foot was found to have significantly longer GCT in Segments 2–4 (−3.13% to −7.79%; ES = −0.38 to −1.29), higher push-off (3.83% to 4.39%; ES = 0.31 to 0.41), and segment-specific SL changes. Inside–outside foot asymmetries are driven by the linear-curvilinear demands of specific segments, peaking in Segment 3 where stabilization demands are greatest. These findings highlight the need for segment-specific training that develops inside-foot stability and outside-foot propulsion to optimize base-running performance in base runners.